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Fatty acids methyl esters from vegetable oil by means of ultrasonic energy.

Stavarache C, Vinatoru M, Nishimura R, Maeda Y

Costin D. Nenitzescu Institute of Organic Chemistry, 71141 Bucharest, P.O. Box 15-254, Romania.

The transesterification of vegetable oil with short-chain alcohols, in the presence of base-catalyst, by means of low frequency ultrasound (28 and 40 kHz) in order to obtain biodiesel fuel was studied. By using ultrasounds the reaction time is much shorter (10-40 min) than for mechanical stirring. The quantity of required catalyst is 2 or 3 times lower. The molar ratio of alcohol/oil used is only 6:1. Normal chain alcohols react fast, while secondary and tertiary alcohols show some or no conversion after 60 min of reaction. Surprisingly, 40 kHz ultrasounds are much more effective in the reduction of the reaction time (10-20 min). Twenty eight kilohertz give slightly better yields (98-99%), but longer reaction time, while higher frequencies are not useful at all for the transesterification of fatty acids.

Published 13 December 2004 in Ultrason Sonochem, 12(5): 367-72.
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